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Classic Paper
Roland, A.E. & Smith, E.C.
The Flora of Nova Scotia. Part 2: The Dicotyledons.
Proceedings of the Nova Scotia Institute of Science 26 (Part 4), 1969: 277-743. The Introduction to this work (pp. 279-311) provides an overview of the flora of Nova Scotia, including historical aspects of botanical work in the province, the physical background and the floral elements (they identify seven: Arctic-alpine and boreal disjunct elements, the boreal element, the Canadian element, the Allegenian element, the southwestern flora, plants of the seashore, introduced plants and weeds).
